High-Temperature Ni-Cr-Fe-Mo Alloy for Gas Turbine & Industrial Furnace Applications | AMS 5536 | Special Alloys
Max Service Temp
~1200 °C
What is Hastelloy X? Hastelloy X (UNS N06002) is the high-temperature specialist of the Hastelloy family — a solid-solution nickel-chromium-iron-molybdenum alloy engineered for oxidation resistance, creep strength, and fabricability in gas turbine and industrial furnace service. Unlike C-276 and other corrosion-focused Hastelloys, Hastelloy X is optimized for dry, oxidizing, high-temperature environments to 1100 °C continuous and 1200 °C intermittent. Its ~22% chromium content forms a protective Cr₂O₃ scale, while molybdenum and solid-solution strengthening provide creep resistance and structural integrity at elevated temperature.
Chromium (Cr) ⭐
20.5 – 23%
High-temp oxidation via Cr₂O₃ scale
Molybdenum (Mo) ⭐
8.0 – 10%
Solid-solution & creep strengthening
Carbon (C) ⭐
0.05 – 0.15%
Higher than C-276; supports creep
Iron (Fe)
17 – 20%
Cost-effective solid-solution addition
Tensile (min)
655 MPa
95 ksi
Yield 0.2% (min)
240 MPa
35 ksi
Elongation (min)
35%
High ductility
Hardness
≤100 HRB
Solution-annealed
Melting Range
1260–1355
°C (2300–2470 °F)
Creep Rupture
≈110 MPa
1000 hr @ 815 °C
What is Hastelloy X?
Hastelloy X (UNS N06002) is a nickel-base solid-solution alloy developed in the 1950s specifically for high-temperature structural service. Its nominal chemistry — balance Ni, 22% Cr, 18% Fe, 9% Mo, 0.6% Co, 0.6% W, and controlled carbon — was deliberately formulated to combine oxidation resistance with fabricability and moderate creep strength. The result is the only Hastelloy alloy whose primary design target is high-temperature oxidation, not aqueous corrosion.
The 20.5–23% chromium level is the highest in the Hastelloy family and is responsible for the protective Cr₂O₃ scale that gives Hastelloy X continuous oxidation resistance to 1100 °C and intermittent capability to 1200 °C. Molybdenum contributes solid-solution strengthening and improves resistance to mildly reducing atmospheres, while the substantial iron content lowers raw material cost and improves forgeability compared with fully nickel-base alloys. Because it is not precipitation-hardened, Hastelloy X remains ductile and weldable and does not require the complex aging schedules of alloys such as Inconel 718.
Typical uses include combustion chambers, afterburners, transition ducts, and turbine exhaust components in aerospace and industrial gas turbines, as well as radiant tubes, muffles, retorts, and reformer hardware in industrial furnaces and petrochemical plants. When specifying, remember: Hastelloy X is an oxidation alloy. For aggressive wet-corrosion environments, choose Hastelloy C-276 or C-22; for higher creep strength above 760 °C, consider age-hardenable Inconel 718 or oxide-dispersion-strengthened (ODS) alloys.
Chemical Composition
Per AMS 5536 / ASTM B435 / ASTM B572. Weight percent. Cr, Mo, and C are the defining elements for high-temperature oxidation and creep behavior.
| Element |
Min (%) |
Max (%) |
Role in Alloy |
| Nickel (Ni) |
Balance |
— |
Base element. Provides austenitic matrix, high-temperature toughness, and thermal fatigue resistance. |
| Chromium (Cr) ⭐ |
20.5 |
23.0 |
Hastelloy X key element. Forms the protective Cr₂O₃ scale that enables continuous oxidation resistance to 1100 °C. Highest Cr level in the Hastelloy family. |
| Iron (Fe) |
17.0 |
20.0 |
Substantial solid-solution addition that improves forgeability and reduces cost while maintaining austenitic stability. |
| Molybdenum (Mo) ⭐ |
8.0 |
10.0 |
Hastelloy X key element. Solid-solution strengthening and creep resistance. Improves resistance to mildly reducing and sulfidizing atmospheres at elevated temperature. |
| Cobalt (Co) |
0.5 |
2.5 |
Solid-solution strengthener; contributes to elevated-temperature tensile and stress-rupture strength. |
| Tungsten (W) |
0.2 |
1.0 |
Minor solid-solution strengthener; augments Mo in high-temperature strength. |
| Carbon (C) ⭐ |
0.05 |
0.15 |
Hastelloy X key element. Higher than corrosion Hastelloys. Provides modest carbide strengthening for creep resistance without destroying weldability. |
| Manganese (Mn) |
— |
1.0 |
Deoxidizer; improves hot workability and weld metal soundness. |
| Silicon (Si) |
— |
1.0 |
Deoxidizer; controlled to avoid low-melting nickel-silicide phases in weldments. |
⭐ Elements that define Hastelloy X's high-temperature oxidation and creep performance
Mechanical Properties
Hastelloy X is solid-solution strengthened. Properties are stable after solution annealing and remain ductile across a wide temperature range.
| Condition |
UTS MPa |
YS MPa |
Elongation % |
Hardness |
| Solution-Annealed ← |
≥655 |
≥240 |
≥35 |
≤100 HRB |
| Elastic / Physical Constant (Solution-Annealed) |
Value |
Unit |
| Modulus of Elasticity (tension) |
196 |
GPa (28.4 × 10³ ksi) |
| Shear Modulus |
76 |
GPa (11.0 × 10³ ksi) |
| Poisson's Ratio |
0.30 |
— |
| Stress-Rupture Strength |
≈110 |
MPa @ 1000 hr / 815 °C |
Physical Properties
| Property |
Value |
Unit |
| Density |
8.22 |
g/cm³ |
| Melting Range |
1260 – 1355 |
°C |
| Thermal Conductivity @ 100 °C |
12.8 |
W/(m·K) |
| Thermal Conductivity @ 800 °C |
26.9 |
W/(m·K) |
| Specific Heat |
440 |
J/(kg·K) |
| Electrical Resistivity |
1.18 |
µΩ·m |
| CTE (20 – 100 °C) |
13.1 |
µm/(m·K) |
| CTE (20 – 800 °C) |
16.6 |
µm/(m·K) |
Heat Treatment
Hastelloy X is normally used in the solution-annealed condition. The higher annealing temperature compared with corrosion Hastelloys ensures complete carbide dissolution and optimizes high-temperature ductility.
| Step |
Temperature / Duration |
Purpose & Notes |
| Step 1: Solution Anneal |
1175 °C, rapid air or water cool |
Higher than corrosion Hastelloys. Dissolves carbides, restores ductility, and provides the standard high-temperature microstructure. |
| Step 2: Stabilization |
870 °C / 4 – 8 hr |
Recommended for prolonged service above 760 °C. Improves creep resistance and dimensional stability by controlled carbide precipitation. |
| Step 3: Stress Relief |
480 – 540 °C |
Relieves residual stresses from forming or welding without significantly affecting mechanical properties. |
⚠ Oxidation Service Limit Continuous service maximum is 1100 °C. Above this temperature, Cr₂O₃ scale growth accelerates and spallation becomes significant. For sustained service between 1100 °C and 1200 °C, consider oxide-dispersion-strengthened (ODS) alloys such as MA956 or alloy 602CA.
High-Temperature Corrosion Resistance
Important: Hastelloy X is an oxidation alloy, not a wet-corrosion alloy. Its corrosion performance should be evaluated in dry, high-temperature environments. For aggressive aqueous media, refer to Hastelloy C-276 or C-22.
| Environment |
Rating |
Behavior & Guidance |
| High-Temp Oxidation |
Excellent |
Excellent to 1100 °C continuous, 1200 °C intermittent. The 22% Cr forms a stable Cr₂O₃ scale that resists oxidation in air and combustion gases. |
| Carburization |
Good |
Good resistance in mildly carburizing environments such as heat-treat furnaces. For strongly carburizing service, higher-nickel grades may be preferred. |
| Sulfidation |
Fair to Poor |
Nickel alloys are susceptible to nickel-nickel sulfide (Ni-Ni₃S₂) eutectic attack at 635 °C. Avoid sulfur-bearing reducing atmospheres unless specifically qualified. |
| Aqueous Corrosion |
Comparable to 304 SS |
Not designed for wet corrosion service. Performance is broadly comparable to 304 stainless steel in aqueous media. Do not substitute for C-276 in chemical process environments. |
Hastelloy X vs Competing High-Temperature Alloys
Rating guide: strength, oxidation resistance, creep resistance, fabricability, relative cost.
| Alloy |
Strength |
Oxidation |
Creep |
Fabricability |
| Hastelloy X — $$$ |
★★★ |
★★★★★ |
★★★★★ |
★★★★ |
| Inconel 625 — $$$$$ |
★★★★ |
★★★ |
★★★★ |
★★★★ |
| Inconel 718 — $$$$$ |
★★★★★ |
★★ |
★★ |
★★★ |
| RA330 — $$ |
★★ |
★★★★ |
★★★★ |
★★★ |
Applications
Hastelloy X is selected wherever components must resist oxidation, thermal cycling, and moderate creep simultaneously. Common applications include:
Aerospace gas turbines — combustion chambers, afterburners, transition ducts, turbine exhaust collectors, and flame holders.
Industrial gas turbines — combustor liners, transition pieces, and hot-gas-path hardware requiring long oxidation life.
Industrial furnaces — radiant tubes, muffles, retorts, conveyor belts, and fixtures operating in oxidizing atmospheres up to 1100 °C.
Petrochemical — reformer components, catalyst support grids, and pigtails in steam-methane reforming units.
Applicable Standards
Hastelloy X is covered by aerospace (AMS) and industrial (ASTM, DIN) specifications. HT PIPE supplies material with mill test reports conforming to the standard requested.
| Standard |
Product Form |
| AMS 5536 |
Sheet, strip, and plate — aerospace-quality high-temperature alloy. |
| AMS 5587 |
Welded tubing for high-temperature service. |
| AMS 5754 |
Bars, forgings, and rings — solution heat treated. |
| ASTM B435 |
Plate, sheet, and strip — UNS N06002. |
| ASTM B572 |
Rod — UNS N06002. |
| DIN 2.4665 |
German material designation for Hastelloy X. |
HT PIPE Project Experience
HT PIPE supplied 2.1 tons of Hastelloy X sheet (AMS 5536, 2.0–6.0 mm thickness) for combustor liner repair on industrial gas turbines. The order required grain size ASTM 4–6, 815 °C stress-rupture testing per lot, and full EN 10204 3.1 certification with mill traceability. All lots met the 1000-hour stress-rupture criterion. Material was cut-to-size, edge-conditioned, and delivered within the customer's outage schedule.
For furnace and petrochemical projects, we regularly supply Hastelloy X sheet, plate, and welded tube in ASTM B435 / B572 or AMS specifications with high-temperature test reports. Contact our sales engineers to match certification and heat treatment to your service conditions.
Frequently Asked Questions
Q1: What makes Hastelloy X different from other Hastelloys?
Hastelloy X is the only Hastelloy designed primarily for high-temperature oxidation, not wet corrosion. Its ~22% Cr is significantly higher than C-276 (~15–16% Cr) and enables the protective Cr₂O₃ scale needed for gas turbine and furnace service. For chemical process corrosion, C-276 or C-22 remain the better choices.
Q2: What is the maximum continuous temperature for Hastelloy X?
1100 °C continuous, 1200 °C intermittent. Above 1100 °C continuous, Cr₂O₃ scale growth accelerates and component life drops rapidly. For sustained 1100–1200 °C service, consider ODS alloys.
Q3: Can Hastelloy X be welded?
Yes — Hastelloy X has exceptional weldability. Use ERNiCrMo-2 filler metal (AWS A5.14) for GTAW or GMAW. Because it is a solid-solution alloy, no post-weld aging is required. A solution anneal at 1175 °C may be applied after heavy fabrication to restore optimum ductility.
Q4: How does Hastelloy X compare to Inconel 625 for high-temperature service?
Hastelloy X wins on maximum service temperature (1200 °C intermittent vs ~980 °C for 625) and oxidation resistance above 1000 °C. Inconel 625 wins on room-temperature strength, wet corrosion resistance (especially seawater and chlorides), and fatigue resistance. Choose X for furnace and turbine hot zones; choose 625 for corrosive lower-temperature service or higher strength.
Q5: Is Hastelloy X magnetic?
No. Hastelloy X is fully austenitic and paramagnetic in the solution-annealed condition. It shows no ferromagnetic response, which is useful for instrumentation and applications sensitive to magnetic fields.
Request a Quote for Hastelloy X
HT PIPE supplies Hastelloy X sheet, plate, bar, welded tube, and custom fabricated parts. Send your specification — sizes, quantities, standard, and testing requirements — and we will quote within 24 hours with full MTC details.
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