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STANDARDS

ASTM B337Download

ASTM B337/B337M is the standard specification by ASTM International covering seamless and welded titanium and titanium alloy pipe for corrosive service. The specification defines multiple grades of commercially pure (CP) titanium and titanium alloys — including Grade 1, Grade 2, Grade 3, Grade 4, Grade 7, Grade 9, and Grade 12 — with pipe dimensions governed by ASME B36.19M. Grade 2 is the industry standard for chemical processing, seawater, and desalination applications. The companion specification ASME SB337 adopts identical requirements for ASME Boiler and Pressure Vessel Code compliance.

Zhengzhou Huitong (HT Pipe) supplies ASTM B337 / SB337 compliant seamless and welded titanium pipe in all standard grades with full Mill Test Certificates (MTC) per EN 10204 3.1

1. Standard Scope & Designation

ASTM B337/B337M covers two manufacturing forms for titanium and titanium alloy pipe:

Form Manufacturing Process Size Range (OD) Weld Test
Seamless (S) Hot pilgered or rotary pierced from ingot/billet 1/2" – 24" (12.7–610 mm) Not applicable
Welded (W) Rolled strip/plate formed, longitudinal weld seam 1/2" – 24" (12.7–610 mm) Weld expansion or hydrostatic required
Scope Statement (ASTM B337/B337M): "This specification covers seamless and welded titanium and titanium alloy pipe in the sizes and schedules included in ASME B36.19M. Pipe shall be suitable for corrosive service and for bending, flanging, and similar forming operations."
Designation Issuing Body Unit System Dimension Standard Latest Edition
ASTM B337 ASTM International Inch-Pound ASME B36.19M B337/B337M-10 (Reapproved)
ASTM B337M ASTM International SI (Metric) ASME B36.19M B337/B337M-10 (Reapproved)
ASME SB337 ASME (BPVC Sec. II Part B) Both ASME B36.19M 2023 Edition

2. Grades Covered by ASTM B337

ASTM B337 covers both commercially pure (CP) titanium grades and titanium alloy grades. Grade 2 is the most widely used for general corrosion-resistant service; Grade 7 adds palladium for enhanced crevice corrosion resistance.

Grade UNS No. Type Key Features
Grade 1 R50250 CP Titanium Highest ductility (40% El), softest; excellent formability for complex shapes
Grade 2 R50400 CP Titanium Most common; best balance of strength, ductility, and corrosion resistance
Grade 3 R50550 CP Titanium Higher strength than Grade 2; used where greater mechanical properties needed
Grade 4 R50700 CP Titanium Highest CP strength; good ductility; aerospace and cryogenic applications
Grade 5 R56400 Ti-6Al-4V (α-β alloy) Highest strength; minimum TS 895 MPa; aerospace and high-stress corrosive service
Grade 7 R52400 CP Ti + Pd (0.12–0.25%) Grade 2 equivalent + Pd; superior crevice corrosion resistance in chlorides
Grade 9 R56320 Ti-3Al-2.5V (α alloy) Higher strength than CP grades; good formability; hydraulic and aerospace tubing
Grade 12 R53400 Ti-0.3Mo-0.8Ni Enhanced high-temp strength; good creep resistance; excellent in reducing acids

3. Chemical Composition (ASTM B337 Table 1)

Values are maximum unless shown as a range. Heat analysis. Ti = balance. Per ASTM B337/B337M-10.

Element Grade 1 (%) Grade 2 (%) Grade 3 (%) Grade 4 (%) Grade 7 (%) Notes
Carbon (C) 0.10 max 0.10 max 0.10 max 0.10 max 0.10 max All grades
Iron (Fe) 0.20 max 0.30 max 0.30 max 0.50 max 0.30 max Strength driver in CP grades
Oxygen (O) 0.18 max 0.25 max 0.35 max 0.40 max 0.25 max Interstitial strengthener
Nitrogen (N) 0.03 max 0.03 max 0.05 max 0.05 max 0.03 max
Hydrogen (H) 0.015 max 0.015 max 0.015 max 0.015 max 0.015 max Critical for embrittlement
Palladium (Pd) 0.12–0.25 Grade 7 only; crevice corrosion resistance
Aluminum (Al) See alloy composition tables for Gr.5, 9, 12
Vanadium (V)
Molybdenum (Mo)
Nickel (Ni) Grade 12: 0.3Mo-0.8Ni

Note: Full chemistry per ASTM B337/B337M-10 Table 1. Product analysis tolerances per ASTM B348 apply. Grade 5: Al 5.5–6.75%, V 3.5–4.5%; Grade 9: Al 2.5–3.5%, V 2.0–3.0%; Grade 12: Mo 0.2–0.4%, Ni 0.6–0.9%.

4. Mechanical Property Requirements (ASTM B337 Table 2)

All values are minimum requirements. Per ASTM B337/B337M-10. All grades supplied in annealed condition.

Grade Tensile Strength
min MPa (ksi)
Yield Strength (0.2% EUL)
min MPa (ksi)
Elongation (min %)
Grade 1 240 (35) 170 (25) 24 (2" GL); 30 (4D)
Grade 2 344 (50) 275 (40) 20 (2" GL); 25 (4D)
Grade 3 450 (65) 380 (55) 18 (2" GL); 22 (4D)
Grade 4 550 (80) 480 (70) 15 (2" GL); 20 (4D)
Grade 5 895 (130) 828 (120) 10 (2" GL); —
Grade 7 344 (50) 275 (40) 20 (2" GL); 25 (4D)
Grade 9 620 (90) 515 (75) 15 (2" GL); —
Grade 12 483 (70) 345 (50) 18 (2" GL); 22 (4D)

Note: Elongation test specimen: 2" gauge length (GL) per ASTM B338 strip specimen, or 4D (4× diameter) for round specimens. EUL = Extension Under Load method. Testing per ASTM E8/E8M.

CP Titanium Strength-Formability Trade-off: As oxygen content increases from Grade 1 (0.18% max O) to Grade 4 (0.40% max O), tensile strength increases from 240 MPa to 550 MPa, but ductility decreases from 24% to 15% elongation. Grade 2 (0.25% max O) offers the optimal balance for most piping applications, and is by far the most widely specified CP titanium grade.

5. Heat Treatment Requirements

Grade Type Required Condition Heat Treatment
CP Grades (1, 2, 3, 4) Annealed Full anneal at 600–700°C (1110–1290°F), air cool or water quench
Grade 7 (Ti-Pd) Annealed Same as CP grades; Pd does not affect HT requirement
Grade 5 (Ti-6Al-4V) Annealed or Solution Treated + Aged Solution treat at 935–955°C; age at 540–605°C for maximum strength
Grade 9 (Ti-3Al-2.5V) Annealed (per ASTM B337) 650–760°C (1200–1400°F), air cool; may be used in cold-drawn condition
Grade 12 (Ti-0.3Mo-0.8Ni) Annealed 590–675°C (1100–1250°F), air cool or water quench
Critical Note on Hydrogen: Hydrogen content in titanium must be controlled to ≤ 0.015% maximum. Hydrogen pickup during heat treatment (especially in air furnaces) or pickling must be avoided — hydrogen embrittlement degrades ductility and fracture toughness. Use vacuum furnaces or controlled-atmosphere heat treatment for best results.

6. Testing & Inspection Requirements

Test Requirement Reference Standard
Chemical Analysis (Heat) One per heat; all elements per Table 1 ASTM B337 Table 1
Tensile Test One per lot (per heat/lot combination); verifies TS, YS, Elongation ASTM E8 / E8M
Flattening Test Welded pipe: one per lot — bend 90° around a mandrel ASTM B337
Weld Expansion Test Welded pipe: one per lot — weld expanded 50% of original OD ASTM B337
Hydrostatic Test Each pipe; test pressure per agreed specification or calculated from design stress ASTM B337
Nondestructive Test (NDE) Eddy current, ultrasonic, or hydrostatic as substitute per agreement ASTM E215 / E213
Visual & Dimensional Inspection OD tolerance ±0.75% (min ±0.25 mm); WT −0 / +15%; straightness 1.5 mm/1000 mm ASTM B337

7. Pipe Dimensions — ASME B36.19M (Stainless Steel & Titanium Pipe)

ASTM B337 pipe dimensions follow ASME B36.19M (Stainless Steel and Titanium Pipe). Key wall thicknesses for common NPS sizes:

NPS OD (mm) Sch 5S
(mm)
Sch 10S
(mm)
Sch 20S
(mm)
Sch 40S
(mm)
Sch 80S
(mm)
Sch 160S
(mm)
1/2 21.34 1.65 2.11 2.77 3.73 4.78
3/4 26.67 1.65 2.11 2.87 3.91 5.56
1 33.40 1.65 2.77 3.38 4.55 6.35
1-1/2 48.26 1.65 2.77 3.68 5.08 7.14
2 60.33 1.65 2.77 3.91 5.54 8.74
3 88.90 2.11 3.05 5.49 7.62 11.13
4 114.30 2.11 3.05 6.02 8.56 13.49
6 168.28 2.11 3.40 7.11 10.97 18.26
8 219.08 2.11 3.76 6.35 8.18 12.70 18.26
10 273.05 2.11 3.96 7.80 9.27 12.70 15.09
12 323.85 2.77 4.57 8.38 9.53 12.70 17.48

Note: ASME B36.19M covers titanium pipe in Schedules 5S, 10S, 20S, 40S, 80S, 120S, and 160S. Unlike B36.10M, the S-suffix schedules have thinner walls for corrosive service (no pressure design in corrosive medium). Wall thickness tolerance: OD ±0.75% (min ±0.25 mm); WT −0 / +15%.

8. Industries & Applications

Industry Recommended Grade Typical Service Media
Desalination Plants Grade 2 / Grade 7 Brine, seawater, evaporator condensate
Chemical Processing Grade 2 / Grade 7 HCl, H₂SO₄, HNO₃, organic acids, chlorides
Offshore & Marine Grade 2 / Grade 7 Seawater cooling lines, topside piping, risers
Power Plant Condensate Grade 2 Condensate piping, feedwater heaters, steam surface condensers
Pulp & Paper Grade 2 / Grade 12 Bleach plant chloride solutions, sodium hypochlorite
Aerospace & Defense Grade 5 / Grade 9 Hydraulic lines, fuel systems, airframe structural piping

9. ASTM B337 vs ASTM B861 vs ASTM B338 — Titanium Pipe & Tube Comparison

Criteria ASTM B337 (Pipe) ASTM B861 (Seamless Pipe) ASTM B338 (Tube)
Product Form Seamless + Welded Pipe Seamless Pipe only Seamless + Welded Tube
Min OD (NPS) 1/2" NPS 3/8 OD to 2" (tube)
Max OD 24" Per agreement 5" OD (tube)
Wall Thickness B36.19M Sched 5S–160S B36.19M Sched 5S–160S BWG or decimal inches
Dimension Standard ASME B36.19M ASME B36.19M ASTM B338 (OD/WT)
Hydrostatic Test Mandatory (each pipe) Mandatory (each pipe) Mandatory or NDE per agreement
Typical Application Chemical piping, offshore flowlines High-pressure chemical, aerospace Heat exchangers, condensers, hydraulic
Key Distinction: ASTM B337 and B861 are pipe specifications governed by ASME B36.19M with pressure-rated wall schedules. ASTM B338 covers tube (smaller OD, thinner walls) typically used for heat exchangers, condensers, and instrumentation where thermal performance or flow dynamics drive the size selection rather than pressure rating alone.

10. Related Standards

Standard Scope Relationship to B337
ASME B36.19M Stainless Steel & Titanium Pipe — OD, Wall, Weight Mandatory dimension standard for B337 pipe
ASME SB337 ASME BPVC Section II Part B — Boiler Code adoption Identical requirements; used for code-stamped pressure systems
ASTM B348 Titanium and Titanium Alloy Billets & Bars Source material specification for pipe extrusion/billing
ASTM B338 Seamless & Welded Titanium Tubes for Heat Exchangers Complementary tube spec; B337 is pipe (pressure-rated)
ASTM B861 Seamless Titanium Pipe (larger sizes, same grades) Seamless-only pipe equivalent of B337
ASTM E8/E8M Tensile Testing of Metallic Materials Governs tensile, yield, elongation test procedures
AWS A5.16 / ERTi Titanium and Titanium Alloy Welding Consumables ERTi-1, ERTi-2, ERTi-7 filler wires for GTAW/GMAW welding
ASME B31.3 Process Piping Code Governs allowable stress & design for B337 titanium process piping

11. How to Order — Required Information

No. Item Requirement / Example
1 Specification ASTM B337 / ASME SB337
2 Grade Grade 2 (most common), Grade 7, Grade 1, Grade 3, Grade 4, Grade 5, Grade 9, Grade 12
3 Manufacturing Form Seamless (S) or Welded (W)
4 NPS & Schedule e.g., NPS 4 Schedule 10S or NPS 6 Schedule 40S per ASME B36.19M
5 Length Single Random (~6 m), Double Random (~11.5 m), or Cut-to-length
6 End Preparation Plain End (PE), Beveled End (BE per ASME B16.25), or Mechanical Joint
7 Service Conditions Temperature range, corrosive media (HCl, H₂SO₄, seawater, etc.)
8 Certification EN 10204 3.1 or 3.2 Certified Mill Test Report (CMTR)
9 Quantity Lineal meters or metric tons (MT)
Download ASTM B337 / B337M Standard (PDF)

The official ASTM B337/B337M PDF is available from our HT Pipe Download Center. The document covers seamless and welded titanium pipe in all grades, including full chemical composition tables, mechanical property requirements, dimensional tolerances, and testing provisions.

Go to Download Center  |  Request MTC / Quotation

12. Frequently Asked Questions

Q: What is ASTM B337 Grade 2 titanium pipe used for?

ASTM B337 Grade 2 (UNS R50400) is the most widely specified titanium pipe for corrosive service. Key applications include seawater desalination plant piping (evaporators, brine heaters, condensate lines), offshore platform seawater cooling systems, chemical processing plant piping for hydrochloric acid, sulfuric acid, nitric acid, and organic acids, and power plant condensate and feedwater systems. Its minimum tensile strength of 344 MPa, yield of 275 MPa, and 20% elongation provide excellent structural integrity while maintaining titanium's superior corrosion resistance in oxidizing and chloride-bearing environments.

Q: What is the difference between ASTM B337 Grade 2 and Grade 7?

Grade 7 (UNS R52400) has identical mechanical properties to Grade 2 — same TS ≥ 344 MPa, YS ≥ 275 MPa, Elongation ≥ 20% — but adds 0.12–0.25% palladium. This palladium addition dramatically improves crevice corrosion resistance in chloride-bearing acids (hydrochloric acid, sulfuric acid, phosphoric acid) and seawater service where crevices are unavoidable. The rule of thumb: specify Grade 7 wherever crevice corrosion is a concern; use Grade 2 for general corrosive service where cost is a factor.

Q: What are the temperature limits for ASTM B337 titanium pipe?

CP titanium grades (Grade 1–4) are limited to approximately 315–400°C (600–750°F) for continuous service. Below 315°C, CP titanium maintains excellent corrosion resistance in most environments. At elevated temperatures above 350°C, CP titanium may experience surface oxidation and gradual strength loss. Grade 5 (Ti-6Al-4V) is limited to approximately 430°C (800°F) due to its alpha-beta microstructure. For cryogenic service, CP titanium grades maintain excellent toughness and ductility down to liquid nitrogen temperature (−196°C) and below, making them suitable for LNG applications.

Q: Can ASTM B337 welded titanium pipe withstand seawater service?

Yes. ASTM B337 Grade 2 and Grade 7 welded titanium pipe are the preferred materials for seawater service. Titanium forms a stable, passive TiO₂ film that provides outstanding corrosion resistance in seawater at temperatures up to approximately 120°C (250°F) with zero pitting, no crevice corrosion (Grade 7), and negligible corrosion rates compared to stainless steels or nickel alloys. Welded titanium pipe for seawater must use ERTi-2 filler wire for Grade 2 base metal, and both the OD and ID weld zone must be purged with argon shielding during and after welding to prevent oxidation embrittlement.

Q: Is ASME SB337 the same as ASTM B337?

Technically identical in chemical, mechanical, dimensional, and testing requirements. ASME SB337 is ASTM B337 adopted into ASME BPVC Section II Part B. The key difference is regulatory context: SB337 is used for ASME Code-stamped pressure vessels and piping where authorized inspector (AI) oversight, Certified Material Test Reports (CMTR), and material traceability are mandatory. For non-code chemical processing or offshore piping, ASTM B337 is sufficient. Most titanium pipe mills supply dual-certified B337/SB337 material.

Request a Quote — ASTM B337 Seamless & Welded Titanium Pipe

Zhengzhou Huitong (HT Pipe) supplies ASTM B337 / SB337 Grade 1, 2, 3, 4, 7, 9, and 12 seamless and welded titanium pipe in all standard schedules. Full EN 10204 3.1 CMTRs and competitive lead times from affiliated titanium mills.