ASTM B463/B463M is the standard specification by ASTM International covering UNS N08020 nickel-iron-chromium alloy plate, sheet, and strip — commonly known as Alloy 20 (or Alloy 20Cb-3). This niobium-stabilized austenitic alloy delivers outstanding resistance to sulfuric acid across a wide range of concentrations and temperatures, with excellent resistance to intergranular corrosion in the as-welded condition. The companion specification ASME SB463 adopts identical requirements for ASME Code-stamped equipment.
Zhengzhou Huitong (HT Pipe) supplies ASTM B463 / ASME SB463 compliant plate, sheet & strip with full Mill Test Certificates (MTC) per EN 10204 3.1.
1. Standard Scope & Designation
ASTM B463/B463M covers UNS N08020 (Alloy 20) plate, sheet, and strip for general corrosion-resistant applications, particularly in sulfuric acid environments. Alloy 20, stabilized with columbium (niobium), provides excellent resistance to intergranular corrosion in the as-welded condition without post-weld heat treatment.
| Form |
Manufacturing Process |
Size Range |
Typical Thickness/Tolerance |
| Plate / Sheet / Strip |
Hot-rolled or cold-rolled from ingot/billet per standard |
ASTM B463 covers plate, sheet, and strip in standard mill thicknesses from thin strip (~0.010 in) to plate up to 3 in (76 mm). Widths and lengths per mill capability; standard widths 48–96 in (1220–2440 mm). Cold-rolled sheet typically available 0.018–0.187 in (0.46–4.75 mm). |
Per standard / purchaser agreement |
Scope Statement (ASTM B463/B463M): "This specification covers UNS N08020, N08024, and N08026 plate, sheet, and strip intended for general corrosive service, with particular suitability for sulfuric acid environments."
| Designation |
Issuing Body |
Unit System |
Dimension Standard |
Latest Edition |
| ASTM B463 |
ASTM International |
Inch-Pound |
ASTM A480/A480M |
B463/B463M-21 |
| ASTM B463M |
ASTM International |
SI (Metric) |
ASTM A480/A480M |
B463/B463M-21 |
| ASME SB463 |
ASME (BPVC Sec. II Part B) |
Both |
ASTM A480/A480M |
2023 Edition |
2. Grades Covered by ASTM B463
ASTM B463 covers the following grades. Each grade is defined by its UNS number and specific chemistry targeted at different service environments.
| Grade / UNS |
Key Chemistry Requirements |
Mechanical Properties (min) |
| Alloy 20 (N08020) |
Ni 32.0–38.0, Cr 19.0–21.0, Cu 3.0–4.0, Mo 2.0–3.0, Cb 8×C–1.00 |
Annealed: TS ≥ 551 MPa (80 ksi), YS ≥ 241 MPa (35 ksi), El ≥ 30% |
| Alloy 20Cb-3 (N08020) |
Same as N08020 with Cb (Nb) stabilization |
Identical mechanical properties; improved IGC resistance |
3. Chemical Composition
Values are weight percent maximum unless shown as a range. Heat analysis. Per ASTM B463 Table 1.
| Ni |
Cr |
Fe |
Cu |
Mo |
C |
Mn |
Si |
S |
P |
Cb+Ta |
Notes |
| Ni |
32.0–38.0 |
Provides sulfuric acid resistance; austenite stabilizer |
— |
| Cr |
19.0–21.0 |
General corrosion and oxidation resistance |
— |
| Fe |
Balance (~31–44) |
Balance |
— |
| Cu |
3.0–4.0 |
Enhances resistance to sulfuric acid |
— |
| Mo |
2.0–3.0 |
Pitting and crevice corrosion resistance in chlorides |
— |
| C |
0.07 max |
Stabilized by Cb; prevents IGC |
— |
| Mn |
2.00 max |
Deoxidizer |
— |
| Si |
1.00 max |
— |
— |
| S |
0.035 max |
— |
— |
| P |
0.045 max |
— |
— |
| Cb+Ta |
8×C min – 1.00 max |
Critical stabilizer against intergranular corrosion |
— |
4. Mechanical Property Requirements
All values are minimum requirements. Tensile testing per ASTM E8/E8M.
| Grade / Condition |
Heat Treatment |
TS min MPa (ksi) |
YS min MPa (ksi) |
El min (%) |
| Alloy 20 — Plate |
Annealed |
551 (80) |
241 (35) |
30 |
| Alloy 20 — Sheet |
Annealed |
551 (80) |
241 (35) |
30 |
| Alloy 20 — Strip |
Annealed |
551 (80) |
241 (35) |
30 |
5. Heat Treatment Requirements
| Grade |
Temperature Range |
Cooling Method |
Purpose |
| Alloy 20 |
940–1010°C (1725–1850°F) |
Rapid air cool or water quench |
Solution anneal to dissolve carbides |
| Stabilization (optional) |
870–900°C (1600–1650°F) |
Air cool |
Precipitate NbC; optional for critical IGC resistance |
6. Testing & Inspection Requirements
| Test |
Requirement |
Reference Standard |
| Chemical Analysis (Heat) |
One per heat; all elements per ASTM B463 Table 1 |
ASTM B463 Table 1 |
| Tensile Test |
One per lot; tensile per ASTM E8/E8M |
ASTM E8 / E8M |
| Hardness Test |
Brinell or Rockwell B per agreement |
ASTM E10 / E18 |
| Intergranular Corrosion (IGC) |
Per ASTM A262 Practice B or E when specified |
ASTM A262 Practice B/E |
| Ultrasonic |
Per ASTM A578 or per agreement |
ASTM A578/A578M |
| Visual & Dimensional |
Thickness tolerance per ASTM A480; flatness per agreement |
ASTM B463 / A480 |
7. Dimensions & Dimensional Tolerances
ASTM B463 covers plate, sheet, and strip in standard mill thicknesses from thin strip (~0.010 in) to plate up to 3 in (76 mm). Widths and lengths per mill capability; standard widths 48–96 in (1220–2440 mm). Cold-rolled sheet typically available 0.018–0.187 in (0.46–4.75 mm).
8. Industries & Applications
| Industry |
Recommended Grade |
Typical Service Media / Application |
| Chemical Processing |
Alloy 20 |
Sulfuric acid service — tanks, piping, heat exchangers |
| Petrochemical |
Alloy 20 |
Solvent extraction, organic acids, mixed acid systems |
| Pharmaceutical |
Alloy 20 |
Reaction vessels, process piping, storage tanks for acids |
| Food Processing |
Alloy 20 |
Acidic food product processing equipment |
| Pickling & Plating |
Alloy 20 |
Sulfuric acid pickling tanks, plating bath liners |
| Pulp & Paper |
Alloy 20 |
Digester components, bleach plant acid piping |
9. ASTM B463 vs ASTM B625 (Ni-Fe-Cr-Mo-Cu Alloy Plate — UNS N08904 / 904L) — Comparison
| Standard |
ASTM B463 (Alloy 20) |
ASTM B625 (904L) |
| UNS |
N08020 |
N08904 |
| Ni Content |
32.0–38.0% |
23.0–28.0% |
| Cr Content |
19.0–21.0% |
19.0–23.0% |
| Mo Content |
2.0–3.0% |
4.0–5.0% |
| Cu Content |
3.0–4.0% |
1.0–2.0% |
| Stabilized (Cb) |
Yes — Nb-stabilized |
No — unstabilized |
| PREN |
~27–30 |
~34–39 |
| Best Application |
Sulfuric acid, all concentrations at moderate T |
Chloride pitting resistance; seawater |
| As-Welded IGC Resistance |
Excellent (stabilized) |
Moderate (PWHT recommended) |
Key Distinction: Alloy 20 (B463) is uniquely optimized for sulfuric acid resistance with high Ni + Cu content and Nb stabilization. Alloy 904L (B625) has higher Mo for superior chloride pitting resistance but lacks stabilization, requiring PWHT for critical IGC resistance. Select B463 for sulfuric acid service; B625 for chloride-rich environments.
10. Related Standards
| Standard |
Scope |
Relationship |
| ASTM B729 |
Alloy 20 Seamless Pipe & Tube (N08020) |
Complementary tubular product standard for same alloy |
| ASTM B464 |
Alloy 20 Welded Pipe (UNS N08020) |
Welded pipe in same alloy for process piping |
| ASTM B473 |
Alloy 20 Bar and Wire |
Bar stock for machined components, fasteners |
| ASME SB463 |
ASME BPVC Section II Part B |
Identical for code-stamped equipment |
| ASTM A262 |
Detecting Susceptibility to IGC |
Practice B (Streicher) or E (Strauss) for IGC verification |
| ASTM B625 |
Ni-Fe-Cr-Mo-Cu Alloy Plate (904L — N08904) |
Higher Mo alternative for chloride service |
| ASTM E8/E8M |
Tensile Testing of Metallic Materials |
Governs tensile, yield, elongation |
| NACE MR0175/ISO 15156 |
Sulfide Stress Cracking Resistant Materials |
Alloy 20 is acceptable for sour service up to certain limits |
11. How to Order — Required Information
| No. |
Item |
Requirement / Example |
| 1 |
Specification |
ASTM B463 / ASME SB463 |
| 2 |
Grade / UNS |
UNS N08020 (Alloy 20) |
| 3 |
Product Form |
Plate, Sheet, or Strip |
| 4 |
Dimensions |
Thickness × Width × Length |
| 5 |
Condition |
Hot-rolled, cold-rolled, annealed, or pickled |
| 6 |
Surface Finish |
No. 1 (HRAP), No. 2D, No. 2B, or per agreement |
| 7 |
IGC Test (optional) |
ASTM A262 Practice B or E when as-welded IGC resistance required |
| 8 |
Certification |
EN 10204 3.1 or 3.2 CMTR |
| 9 |
Quantity |
Pieces, MT, or total area (m² / ft²) |
Download ASTM B463 Standard (PDF)
The official ASTM B463 PDF is available from our HT Pipe Download Center. The document covers UNS N08020 Alloy Plate, Sheet, and Strip, including full chemical composition tables, mechanical property requirements, dimensional tolerances, and testing provisions.
Go to Download Center | Request MTC / Quotation
12. Frequently Asked Questions
Q: What is ASTM B463 Alloy 20 used for?
ASTM B463 Alloy 20 (UNS N08020) plate is primarily used in sulfuric acid service — including storage tanks, reaction vessels, heat exchanger tube sheets, and process piping — across concentrations from dilute to 98% at moderate temperatures. It is also specified for phosphoric acid, nitric acid, organic acids, and mixed acid systems in chemical processing, pharmaceutical, and petrochemical industries. Its niobium stabilization ensures excellent intergranular corrosion resistance in the as-welded condition, eliminating the need for post-weld heat treatment in many applications.
Q: What is the difference between Alloy 20 and 316L stainless steel?
Alloy 20 contains significantly higher nickel (32–38% vs 10–14%) and copper (3–4% vs none) than 316L, giving it dramatically superior resistance to sulfuric acid at all concentrations. While 316L is rapidly attacked by sulfuric acid at concentrations above 5%, Alloy 20 maintains excellent corrosion resistance up to approximately 40% H₂SO₄ at boiling point. Additionally, Alloy 20's niobium stabilization prevents sensitization during welding, whereas 316L can still experience intergranular attack in certain environments despite its low-carbon designation.
Q: Can ASTM B463 Alloy 20 plate be welded without PWHT?
Yes, this is one of Alloy 20's key advantages. The niobium (columbium) stabilization — minimum 8× carbon content, maximum 1.00% — precipitates NbC preferentially during welding, preventing chromium carbide (Cr₂₃C₆) formation at grain boundaries. This makes Alloy 20 highly resistant to intergranular corrosion (sensitization) in the as-welded condition, eliminating the mandatory post-weld heat treatment required for unstabilized austenitic stainless steels. Recommended filler metal: ERNiCrMo-3 (AWS A5.14) or E/ERNiCrMo-3 for GTAW/SMAW.
Q: What is PREN and where does Alloy 20 rank?
PREN (Pitting Resistance Equivalent Number) = %Cr + 3.3×%Mo + 16×%N. For Alloy 20 (Cr 19–21%, Mo 2–3%, N ~0.04% typical), PREN ≈ 27–30 — comparable to 316L (~24–27) but lower than 904L (~34–39) or super-austenitics like AL-6XN (~43–48). Alloy 20 should not be selected purely for chloride pitting resistance; its strength is sulfuric acid service, where PREN is not the controlling parameter. For seawater or high-chloride service, consider ASTM B688 (AL-6XN, PREN ~43–48) or ASTM B575 (Alloy C-276, PREN ~64+).
Q: What is the temperature limit for ASTM B463 Alloy 20?
For continuous service in sulfuric acid environments, Alloy 20 is typically limited to approximately 170°C (338°F) depending on acid concentration. In general corrosive service without sulfuric acid, it can be used up to approximately 540°C (1000°F), though mechanical properties begin to decrease above 400°C (750°F). For elevated-temperature structural applications, Alloy 800H/800HT (ASTM B409) or Alloy 625 (ASTM B443) should be considered. Cryogenic service is acceptable — Alloy 20 retains good toughness down to −196°C (−320°F).
Request a Quote — ASTM B463 Alloy 20 (UNS N08020) Plate, Sheet & Strip
Zhengzhou Huitong (HT Pipe) supplies ASTM B463 / SB463 UNS N08020 Alloy 20 plate, sheet, and strip for sulfuric acid and general corrosive service. Full EN 10204 3.1 CMTRs with IGC testing per ASTM A262 when specified. Competitive lead times from qualified nickel alloy mills.